Electronic Detection of Molecule-Surface Interactions

29 June 1987

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It has long been known that surface physical and chemical states can strongly affect and indeed dominate the bulk-averaged electronic properties of a semiconductor, [1] and that semiconductor surfaces can function as chemical detectors. As part of a systematic study of the coupling of surface chemistry to electronic properties, we have measured dramatic changes in recombination lifetimes and resistance due to controlled changes in the physical and chemical state of InP(100) and InP(110) surfaces.