Main content

Solution crystallization of poly(ether ether ketone) (PEEK).

01 January 1986

New Image

The morphology of spherulites and single crystals of poly(ether ether ketone) obtained from two organic solvents (a-chloronaphthalene and benzophenone) has been studied by electron microscopy and diffraction. Spherulites were found to consist of very narrow, elongated lamellar branches that grow with the b-crystallographic axis in the radial direction. Single crystals possess a spear- like habit, with b parallel to the long axis, a transverse, and c (i.e. the molecular axis) normal to the lamellar plane. This habit becomes less anisometric with increasing growth temperature.