Shear Modulus and Specific Heat of the Liquid Crystal Blue Phases.

01 January 1984

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We report high precision measurements of the shear modulus, viscosity and specific heat of Cholesteryl Nonanoate through its blue Phases (BPI-III). Our mechanical measurements as a function of temperature and frequency show clear evidence for the phase sequence Cholesteric ->BPI->BPII->BPIII->Isotropic which agrees with optical measurements and precision specific heat data. For BPI and BPII we find a shear modulus which remains finite as the frequency approaches zero, indicating that they are viscoelestic solids.