Theory of the Flow of Electrons and Holes in Germanium and Other Semiconductors

Theory of the Flow of Electrons and Holes in Germanium and Other Semiconductors B y W . VAN R O O S B R O E C K (Manuscript Received Mar. 30,1950) A theoretical analysis of the flow of added current carriers in homogeneous semiconductors is given. The simplifying assumption is made at the outset t h a t trapping effects may be neglected, and the subsequent treatment is intended particularly for application to germanium. In a general formulation, differential equations and boundary-condition relationships in suitable reduced variables and parameters are derived from fundamental equations which take into account the phenomena of drift, diffusion, and recombination. This formulation is specialized so as to apply to the steady state of constant total current in a single cartesian distance coordinate, and properties of solutions which give the electrostatic field and the concentrations and flow densities of the added carriers are discussed. The ratio of hole to electron concentration at thermal equilibrium occurs as parameter. General solutions are given analytically in closed form for the intrinsic semiconductor, for which the ratio is unity, and for some limiting cases as well. Families of numerically obtained solutions dependent on a parameter proportional to total current are given for «-type germanium for the ratio equal to zero. The solutions are utilized in a consideration of simple boundaryvalue problems concerning a single plane source in an infinite filament. TABLE OF CONTENTS 1.